SnO<sub>2</sub> Films Elaborated by Radio Frequency Magnetron Sputtering as Potential Transparent Conducting Oxides Alternative for Organic Solar Cells

نویسندگان

چکیده

Transparent conducting oxides (TCOs) are a crucial component of solar cells. Tin-doped indium oxide (ITO) is the most employed TCO, but scarcity and high price induce search for lower-cost TCOs with equivalent properties as substitutes. Tin dioxide (SnO2) films have many advantages, such rich sources material, low prices, nontoxicity. SnO2 present visible-light transmittance, near-infrared light reflectivity, excellent electrical properties. They also higher chemical mechanical stability compared to ITO. The aim this work elaborate by radio frequency (RF)-magnetron sputtering in order use them electrodes organic cells (OSCs). were deposited on glass, SiO2, quartz substrates mixed environment Ar O2. X-ray diffraction (XRD) measurements show that as-deposited polycrystalline cassiterite tetragonal structure. Scanning electron microscopy (SEM) analysis showed homogeneous, continuous, nanostructured. resistivity average optical transmittance samples about 10–3 Ω.cm over 80%, respectively. estimated band gap (Eg) around 4.0 eV, while function (WF) 5.0 eV. used inverted OSCs, using poly(3-hexylthiophene-2,5-diyl): [6,6]-phenyl-C60-butryric acid methyl ester (P3HT:PC60BM) active layer. device’s open-circuit voltage (VOC) short-circuit current density (JSC) similar those obtained OSCs employing ITO same electrode. Even if achieved power conversion efficiency (PCE) lower value reference OSC an electrode, these results promising place TCO potential candidate replace

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ژورنال

عنوان ژورنال: ACS applied energy materials

سال: 2021

ISSN: ['2574-0962']

DOI: https://doi.org/10.1021/acsaem.1c02711